Math 2.0

Statistical mechanics, structure of matter Definition

Cluster expansion

Builds on Mayer f-functionGrand canonical ensembleConnected graphPower series

Definition

Let φ ⁣:ℝd→ℝ∪{+∞}\varphi \colon \R^d \to \R \cup \set{+\infty} be an even measurable pair potential that is bounded below, let β>0\beta > 0, and let ff be its Mayer f-function, with fij=f(xi−xj)f_{ij} = f(x_i - x_j). For a bounded region Λ⊂ℝd\Lambda \subset \R^d and an activity z>0z > 0, the grand canonical partition function is ΞΛ(z)=∑n≥0znn!∫Λn∏1≤i<j≤n(1+fij) dx1⋯dxn.\Xi_\Lambda(z) = \sum_{n \ge 0} \frac{z^n}{n!} \int_{\Lambda^n} \prod_{1 \le i < j \le n} (1 + f_{ij}) \, dx_1 \cdots dx_n. For n≥1n \ge 1, let 𝒞n\mathcal{C}_n be the set of connected graphs with vertex set {1,…,n}\set{1, \dots, n}. The cluster expansion (Mayer expansion) of ln⁡ΞΛ\ln \Xi_\Lambda is the power series ln⁡ΞΛ(z)=∑n≥1znn!∫Λn∑G∈𝒞n∏{i,j}∈E(G)fij dx1⋯dxn.\ln \Xi_\Lambda(z) = \sum_{n \ge 1} \frac{z^n}{n!} \int_{\Lambda^n} \sum_{G \in \mathcal{C}_n} \prod_{\set{i, j} \in E(G)} f_{ij} \, dx_1 \cdots dx_n. It holds as an identity of formal power series in zz.

Remarks

In the thermodynamic limit it becomes βp=∑n≥1bnzn\beta p = \sum_{n \ge 1} b_n z^n, with bn=1n!∫(ℝd)n−1∑G∈𝒞n∏{i,j}∈E(G)fij dx2⋯dxnb_n = \frac{1}{n!} \int_{(\R^d)^{n - 1}} \sum_{G \in \mathcal{C}_n} \prod_{\set{i,j} \in E(G)} f_{ij} \, dx_2 \cdots dx_n and x1=0x_1 = 0. Here pp is the pressure, and the bnb_n are the Mayer cluster coefficients. Example: there is one connected graph on one vertex and one on two vertices, so b1=1b_1 = 1 and b2=12∫ℝdf(x) dxb_2 = \frac{1}{2} \int_{\R^d} f(x) \, dx. Non-example: the sum over all graphs, connected or not, gives ΞΛ\Xi_\Lambda itself rather than its logarithm, so it is not the cluster expansion. For stable and regular pair potentials the series for βp\beta p has a positive radius of convergence. Abstract polymer versions replace particles by polymers and ff by an incompatibility relation.

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  1. Connected graph concept
  2. Grand canonical ensemble concept
  3. Mayer f-function concept
  4. Power series concept
  5. Cluster expansion definition

Further reading

  1. Web https://en.wikipedia.org/wiki/Cluster_expansion
About this page
TagJYYGCVH387
URIm2://JYYGCVH387
Kinddefinition
WritingW0 stub
MSC82B05, 82B21, 82B20
DefinesCluster expansion
UsesMayer f-function, Grand canonical ensemble, Connected graph, Power series
Changed3 November 2026

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