Math 2.0

Statistical mechanics, structure of matter Definition

Drude model

Builds on Electric fieldPermittivityLorentz oscillator model

Definition

Let a metal contain n>0n > 0 free electrons per unit volume, each with charge −e<0-e < 0 and mass m>0m > 0. Let τ>0\tau > 0 be the mean time between collisions. Let E(t)E(t) be a spatially uniform electric field. The Drude model assumes that the mean momentum p(t)∈ℝ3p(t) \in \R^3 of an electron obeys dpdt=−pτ−eE(t),\frac{dp}{dt} = -\frac{p}{\tau} - e E(t), and that the current density is J=−ne p/mJ = -n e \, p / m.

Remarks

For a constant field the steady state is p=−eτEp = -e \tau E, so J=σ0EJ = \sigma_0 E with the DC conductivity σ0=ne2τ/m\sigma_0 = n e^2 \tau / m: this is Ohm's law. For a time-harmonic field Re(E0e−iωt)\mathrm{Re}(E_0 e^{-i\omega t}) the steady state gives J=σ(ω)EJ = \sigma(\omega) E with σ(ω)=σ01−iωτ.\sigma(\omega) = \frac{\sigma_0}{1 - i \omega \tau}. The relative permittivity εr=1+iσ/(ε0ω)\varepsilon_r = 1 + i \sigma / (\varepsilon_0 \omega) is then εr(ω)=1−ωp2ω2+iω/τ,ωp2=ne2ε0m.\varepsilon_r(\omega) = 1 - \frac{\omega_p^2}{\omega^2 + i \omega / \tau}, \qquad \omega_p^2 = \frac{n e^2}{\varepsilon_0 m}. This is the Lorentz oscillator model with natural frequency 00 and damping rate 1/τ1/\tau. For ωτ≫1\omega \tau \gg 1, εr\varepsilon_r is close to 1−ωp2/ω21 - \omega_p^2 / \omega^2, negative for ω<ωp\omega < \omega_p, where the metal reflects, and positive for ω>ωp\omega > \omega_p, where it becomes transparent.

Example: in a constant field EE, the function p(t)=−eτE+(p(0)+eτE)e−t/τp(t) = -e\tau E + (p(0) + e\tau E) e^{-t/\tau} solves the equation of motion and tends to the steady state −eτE-e\tau E.

Non-example: electrons bound to atoms by a restoring force do not fit the model. Their equation of motion has the additional term −mω02x-m \omega_0^2 x with ω0>0\omega_0 > 0, and they are described by the Lorentz oscillator model instead.

Reading path

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  1. Electric field concept
  2. Lorentz oscillator model concept
  3. Permittivity concept
  4. Drude model definition

Further reading

  1. Web https://en.wikipedia.org/wiki/Drude_model
About this page
TagZWB92XQPV9
URIm2://ZWB92XQPV9
Kinddefinition
WritingW0 stub
MSC82D35, 78A40, 78A48
DefinesDrude model
UsesElectric field, Permittivity, Lorentz oscillator model
Changed3 November 2026

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