Statistical mechanics, structure of matter Definition
Fermi–Dirac statistics
Builds on Grand canonical ensemble
Definition
Consider a system of non-interacting identical particles in the grand canonical ensemble at temperature and chemical potential . Let be the Boltzmann constant and . The particles obey Fermi–Dirac statistics if each single-particle state is occupied by or particle (the Pauli exclusion principle). Then the mean occupation number of a single-particle state of energy is The function is called the Fermi–Dirac distribution.
Remarks
The formula follows from the grand partition function of one state, , which has one term for each allowed occupation. The mean occupation is , which equals the formula above.
Example: at , . For every , , consistent with at most one particle per state. As , tends to for and to for .
Non-example: Maxwell–Boltzmann statistics gives , which exceeds when , so it violates the exclusion principle. The two agree up to small relative error when .
Integrals of against powers of are Fermi–Dirac integrals.
Reading path
To understand this page from the ground up, read these 2 pages in order. The foundations come first.
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- no evidence level
- Grand canonical ensemble concept
- Fermi–Dirac statistics definition
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About this page
| Tag | G6K7HBJ583 |
|---|---|
| URI | m2://G6K7HBJ583 |
| Kind | definition |
| Writing | W0 stub |
| MSC | 82B10, 81V74 |
| Defines | Fermi–Dirac statistics |
| Uses | Grand canonical ensemble |
| Changed | 3 November 2026 |
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