Math 2.0

Statistical mechanics, structure of matter Definition

Fermi–Dirac statistics

Builds on Grand canonical ensemble

Definition

Consider a system of non-interacting identical particles in the grand canonical ensemble at temperature T>0T > 0 and chemical potential μ∈ℝ\mu \in \R. Let kBk_B be the Boltzmann constant and β=1/(kBT)\beta = 1/(k_B T). The particles obey Fermi–Dirac statistics if each single-particle state is occupied by 00 or 11 particle (the Pauli exclusion principle). Then the mean occupation number of a single-particle state of energy ε\varepsilon is nˉ(ε)=1eβ(ε−μ)+1.\bar n(\varepsilon) = \frac{1}{e^{\beta (\varepsilon - \mu)} + 1}. The function f(ε)=nˉ(ε)f(\varepsilon) = \bar n(\varepsilon) is called the Fermi–Dirac distribution.

Remarks

The formula follows from the grand partition function of one state, 1+e−β(ε−μ)1 + e^{-\beta(\varepsilon - \mu)}, which has one term for each allowed occupation. The mean occupation is e−β(ε−μ)/(1+e−β(ε−μ))e^{-\beta(\varepsilon - \mu)} / (1 + e^{-\beta(\varepsilon - \mu)}), which equals the formula above.

Example: at ε=μ\varepsilon = \mu, nˉ=1/(1+1)=1/2\bar n = 1/(1 + 1) = 1/2. For every ε\varepsilon, 0<nˉ(ε)<10 < \bar n(\varepsilon) < 1, consistent with at most one particle per state. As T→0T \to 0, nˉ(ε)\bar n(\varepsilon) tends to 11 for ε<μ\varepsilon < \mu and to 00 for ε>μ\varepsilon > \mu.

Non-example: Maxwell–Boltzmann statistics gives nˉ=e−β(ε−μ)\bar n = e^{-\beta(\varepsilon - \mu)}, which exceeds 11 when ε<μ\varepsilon < \mu, so it violates the exclusion principle. The two agree up to small relative error when β(ε−μ)≫1\beta(\varepsilon - \mu) \gg 1.

Integrals of ff against powers of ε\varepsilon are Fermi–Dirac integrals.

Reading path

To understand this page from the ground up, read these 2 pages in order. The foundations come first.

Show the path as a graph
Each page uses the pages above it. The colour of the bar on a box shows how strong the evidence is, and the box also gives it as text. The list has the same pages.
  • no evidence level
  1. Grand canonical ensemble concept
  2. Fermi–Dirac statistics definition

Further reading

  1. Web https://en.wikipedia.org/wiki/Fermi%E2%80%93Dirac_statistics
About this page
TagG6K7HBJ583
URIm2://G6K7HBJ583
Kinddefinition
WritingW0 stub
MSC82B10, 81V74
DefinesFermi–Dirac statistics
UsesGrand canonical ensemble
Changed3 November 2026

Markdown · JSON · Edit on GitHub

What this page needs for W1

  • an inventory row: the row of the inventory that the node accounts for (0 of 1)
  • a source with a locator (0 of 1)

The writing levels say how complete the text of a page is. They do not measure its truth.

What links here

No page links to this page yet.