Statistical mechanics, structure of matter Kinetic theory Theorem
H-theorem
Statement
Let be the three-dimensional torus. Let be a collision kernel with almost everywhere. For and put and . Let be a smooth solution on of the Boltzmann equation where , , , and . Assume that decays fast enough in for all the integrals below to converge and for differentiation under the integral sign. Let . Then and at time if and only if, for every , the function is a Maxwell–Boltzmann distribution.
Remarks
The transport term does not change on the torus, since . For the collision term one uses the symmetries and of the collision integral, which have unit Jacobian. Averaging the four resulting expressions gives the formula, and the integrand is because . Equality forces , so is a collision invariant, a combination of , and , and is a Gaussian in .
Example: if is a global Maxwellian, constant in and , then by conservation of momentum and energy in each collision, and is constant.
The physical entropy is , so the theorem says that the entropy of an isolated dilute gas does not decrease. It was proved by Ludwig Boltzmann in 1872.
Going deeper
For a student
The H-theorem gives the a priori bound on that is used in the existence theory for the Boltzmann equation, for instance in the DiPerna–Lions theorem. It also identifies the equilibria of the collision operator, which is the starting point of the Chapman–Enskog theory and of hydrodynamic limits. The apparent conflict with time-reversible mechanics, raised by Loschmidt, is resolved by the fact that the Boltzmann equation already contains the assumption of molecular chaos.
Reading path
To understand this page from the ground up, read these 3 pages in order. The foundations come first.
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- no evidence level
- Boltzmann equation concept
- Maxwell–Boltzmann distribution concept
- H-theorem statement
Where this leads
2 pages build on this one.
Further reading
About this page
| Tag | BMA7D1Z2W6 |
|---|---|
| URI | m2://BMA7D1Z2W6 |
| Kind | statement, theorem |
| Writing | W0 stub |
| MSC | 82C40, 35Q20, 76P05 |
| Status | This copy of the site has no build data. Run m2 status BMA7D1Z2W6. |
| About | Boltzmann equation |
| Uses | Boltzmann equation, Maxwell–Boltzmann distribution |
| Same as | |
| Changed | 3 November 2026 |
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