Math 2.0

Fluid mechanics Definition

Marangoni effect

Builds on Navier–Stokes equationsViscosityNo-slip condition

Definition

Consider a liquid with viscosity μ>0\mu > 0 in the half-space z<0z < 0, below a flat free surface z=0z = 0. Above the surface is a gas of negligible viscosity. Let u=(u1,u2,u3)u = (u_1, u_2, u_3) be the velocity of the liquid, a solution of the Navier–Stokes equations. Let the surface tension σ(x,y)\sigma(x, y) be a smooth function on the surface, for instance through its dependence on the temperature or on a surfactant concentration. The Marangoni effect is the tangential stress ∇sσ=(∂xσ,∂yσ)\nabla_s\sigma = (\partial_x\sigma, \partial_y\sigma) that the surface exerts on the liquid. It enters the boundary condition at z=0z = 0: μ ∂u1∂z=∂σ∂x,μ ∂u2∂z=∂σ∂y,u3=0.\mu\,\frac{\partial u_1}{\partial z} = \frac{\partial\sigma}{\partial x}, \qquad \mu\,\frac{\partial u_2}{\partial z} = \frac{\partial\sigma}{\partial y}, \qquad u_3 = 0. A flow driven by this stress is called a Marangoni flow.

Remarks

Example: let σ(x)=σ0+τx\sigma(x) = \sigma_0 + \tau x with τ>0\tau > 0 constant, and take a liquid layer −d<z<0-d < z < 0 on a solid bottom with the no-slip condition. The steady shear flow u=(τμ(z+d),0,0)u = \left(\frac{\tau}{\mu}(z + d), 0, 0\right) satisfies the Navier–Stokes equations with constant pressure, vanishes at z=−dz = -d, and has μ ∂zu1=τ=∂xσ\mu\,\partial_z u_1 = \tau = \partial_x\sigma at z=0z = 0. So the surface moves towards larger σ\sigma, with speed τd/μ\tau d/\mu. Non-example: if σ\sigma is constant, the condition reduces to ∂zu1=∂zu2=0\partial_z u_1 = \partial_z u_2 = 0, the stress-free condition, and there is no Marangoni stress. For thermal Marangoni convection one uses the Marangoni number Ma=−dσdTΔT Lμα\mathrm{Ma} = -\frac{d\sigma}{dT}\frac{\Delta T\,L}{\mu\alpha}, with ΔT\Delta T a temperature difference, LL a length and α\alpha the thermal diffusivity.

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  1. Navier–Stokes equations concept
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  3. Viscosity concept
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Further reading

  1. Web https://en.wikipedia.org/wiki/Marangoni_effect
About this page
TagNCYXJ5GP62
URIm2://NCYXJ5GP62
Kinddefinition
WritingW0 stub
MSC76D45, 76E06
DefinesMarangoni effect
UsesNavier–Stokes equations, Viscosity, No-slip condition
Changed3 November 2026

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