Math 2.0

Statistical mechanics, structure of matter Definition

Master equation

Builds on Continuous-time Markov chainOrdinary differential equation

Definition

Let SS be a finite or countable set of states. For each pair x≠yx \ne y in SS, let w(x→y)≥0w(x \to y) \ge 0 be a transition rate, and assume ∑y≠xw(x→y)<∞\sum_{y \ne x} w(x \to y) < \infty for every xx. The master equation with these rates is the system of ordinary differential equations ddtPt(x)=∑y≠x(w(y→x) Pt(y)−w(x→y) Pt(x)),x∈S,\frac{d}{dt} P_t(x) = \sum_{y \ne x} \big( w(y \to x) \, P_t(y) - w(x \to y) \, P_t(x) \big), \qquad x \in S, for a family (Pt)t≥0(P_t)_{t \ge 0} of probability distributions on SS.

Remarks

With the matrix Q(x,y)=w(x→y)Q(x, y) = w(x \to y) for x≠yx \ne y and Q(x,x)=−∑y≠xw(x→y)Q(x, x) = -\sum_{y \ne x} w(x \to y), the equation reads ddtPt=PtQ\frac{d}{dt} P_t = P_t Q, with PtP_t as a row vector. This is the Kolmogorov forward equation of the continuous-time Markov chain with rate matrix QQ, and Pt(x)P_t(x) is the probability that the chain is in state xx at time tt. For finite SS the solution is Pt=P0etQP_t = P_0 e^{tQ}.

Example: for S={0,1}S = \set{0, 1} with w(0→1)=aw(0 \to 1) = a and w(1→0)=bw(1 \to 0) = b, where a,b>0a, b > 0, the equation for Pt(1)P_t(1) is ddtPt(1)=aPt(0)−bPt(1)=a−(a+b)Pt(1)\frac{d}{dt} P_t(1) = a P_t(0) - b P_t(1) = a - (a + b) P_t(1). Its solution is Pt(1)=aa+b+(P0(1)−aa+b)e−(a+b)tP_t(1) = \frac{a}{a + b} + \big(P_0(1) - \frac{a}{a + b}\big) e^{-(a + b)t}, which tends to aa+b\frac{a}{a + b}.

Non-example: the system ddtPt(x)=∑y≠xw(y→x)Pt(y)\frac{d}{dt} P_t(x) = \sum_{y \ne x} w(y \to x) P_t(y), without the loss term, is not a master equation; it does not conserve ∑xPt(x)\sum_x P_t(x), so PtP_t does not stay a probability distribution.

A distribution π\pi is stationary when the right side vanishes; it satisfies detailed balance when w(y→x)π(y)=w(x→y)π(x)w(y \to x) \pi(y) = w(x \to y) \pi(x) for all x≠yx \ne y, which is a stronger condition.

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  1. Continuous-time Markov chain concept
  2. Ordinary differential equation concept
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Further reading

  1. Web https://en.wikipedia.org/wiki/Master_equation
About this page
TagH73XWCVKMV
URIm2://H73XWCVKMV
Kinddefinition
WritingW0 stub
MSC82C31, 60J27, 82C05
DefinesMaster equation
UsesContinuous-time Markov chain, Ordinary differential equation
Changed3 November 2026

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