Math 2.0

Optics, electromagnetic theory Scattering Theorem

Mie scattering

Builds on Electromagnetic scatteringElectromagnetic scatteringPlane waveRefractive indexBessel function of the first kindSpherical harmonics

Statement

Let a homogeneous, isotropic, non-magnetic sphere of radius aa lie in a homogeneous non-magnetic medium, with complex refractive index mm relative to the medium. Assume Re⁡m>0\operatorname{Re} m > 0 and Im⁡m≥0\operatorname{Im} m \ge 0. Let it be illuminated by a monochromatic plane wave with wavenumber kk in the medium and time factor e−iωte^{-i\omega t}, and put x=kax = ka. Let ψn(ρ)=ρ jn(ρ)\psi_n(\rho) = \rho\, j_n(\rho) and ξn(ρ)=ρ hn(1)(ρ)\xi_n(\rho) = \rho\, h_n^{(1)}(\rho) be the Riccati–Bessel functions built from the spherical Bessel function jnj_n and the spherical Hankel function hn(1)h_n^{(1)}. Then the scattering problem has a unique solution. Its scattered field is a series over n≥1n \ge 1 of vector spherical wave functions with coefficients given by an=m ψn(mx) ψn′(x)−ψn(x) ψn′(mx)m ψn(mx) ξn′(x)−ξn(x) ψn′(mx),bn=ψn(mx) ψn′(x)−m ψn(x) ψn′(mx)ψn(mx) ξn′(x)−m ξn(x) ψn′(mx).a_n = \frac{m\, \psi_n(mx)\, \psi_n'(x) - \psi_n(x)\, \psi_n'(mx)}{m\, \psi_n(mx)\, \xi_n'(x) - \xi_n(x)\, \psi_n'(mx)}, \qquad b_n = \frac{\psi_n(mx)\, \psi_n'(x) - m\, \psi_n(x)\, \psi_n'(mx)}{\psi_n(mx)\, \xi_n'(x) - m\, \xi_n(x)\, \psi_n'(mx)}. The scattering and extinction cross-sections are Csca=2πk2∑n=1∞(2n+1)(∣an∣2+∣bn∣2),Cext=2πk2∑n=1∞(2n+1)Re⁡(an+bn).C_{\mathrm{sca}} = \frac{2\pi}{k^2} \sum_{n=1}^{\infty} (2n + 1)\left( \abs{a_n}^2 + \abs{b_n}^2 \right), \qquad C_{\mathrm{ext}} = \frac{2\pi}{k^2} \sum_{n=1}^{\infty} (2n + 1) \operatorname{Re}(a_n + b_n).

Remarks

The proof separates variables in spherical coordinates. The incident plane wave is expanded in vector spherical wave functions built from spherical harmonics and spherical Bessel functions. The internal field uses jn(mkr)j_n(mkr) and the scattered field uses hn(1)(kr)h_n^{(1)}(kr). Continuity of the tangential components of 𝐄\mathbf{E} and 𝐇\mathbf{H} on the sphere gives, for each nn, two decoupled pairs of linear equations whose solutions are ana_n and bnb_n. The solution is named after Gustav Mie, who published it in 1908. For x≪1x \ll 1 the leading coefficient a1a_1 dominates and the cross-section reduces to that of Rayleigh scattering. For x≫1x \gg 1 and an absorbing or non-absorbing sphere, the extinction efficiency Cext/(πa2)C_{\mathrm{ext}}/(\pi a^2) tends to 22, twice the geometric cross-section, the extinction paradox. In practice the series is truncated after about x+4x1/3+2x + 4x^{1/3} + 2 terms.

Going deeper

For a student

The solution is a model case of separation of variables for Maxwell's equations and a benchmark for numerical scattering codes. Its coefficients ana_n and bnb_n are the electric and magnetic multipole responses of the sphere; resonances in them give the ripple structure of the cross-sections. Small spheres give Rayleigh scattering, and very large spheres approach geometrical optics with diffraction. The same method extends to coated spheres and, via the T-matrix method, to non-spherical particles.

Reading path

To understand this page from the ground up, read these 10 pages in order. The foundations come first.

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Each page uses the pages above it. The colour of the bar on a box shows how strong the evidence is, and the box also gives it as text. The list has the same pages.
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  1. Bessel function of the first kind concept
  2. Electromagnetic scattering concept
  3. Maxwell's equations concept
  4. Permittivity concept
  5. Plane wave concept
  6. Refractive index concept
  7. Silver–Müller radiation condition concept
  8. Spherical harmonics concept
  9. Electromagnetic scattering definition
  10. Mie scattering statement

Further reading

  1. Web https://en.wikipedia.org/wiki/Mie_scattering
About this page
TagDEBPQR1ZSH
URIm2://DEBPQR1ZSH
Kindstatement, theorem
WritingW0 stub
MSC78A45, 35Q61
StatusThis copy of the site has no build data. Run m2 status DEBPQR1ZSH.
AboutElectromagnetic scattering
UsesElectromagnetic scattering, Electromagnetic scattering, Plane wave, Refractive index, Bessel function of the first kind, Spherical harmonics
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Changed3 November 2026

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