Math 2.0

Quantum theory Definition

Scattering theory

Builds on Hilbert spaceSelf-adjoint operatorUnitary operatorHamiltonian operator

Definition

Let ℋ\mathcal{H} be a complex Hilbert space, and let H0H_0 and HH be self-adjoint operators on ℋ\mathcal{H}, the free and the full Hamiltonian. Let Pac(H0)P_{ac}(H_0) be the orthogonal projection onto the absolutely continuous subspace of H0H_0. The wave operators of the pair (H,H0)(H, H_0) are the strong limits W±=s-lim⁡t→±∞eitHe−itH0Pac(H0),W_\pm = \operatorname*{s-lim}_{t \to \pm\infty} e^{itH} e^{-itH_0} P_{ac}(H_0), when they exist. Scattering theory is the study of these limits and of the following properties.

  1. Existence: both limits W+W_+ and W−W_- exist.
  2. Asymptotic completeness: the ranges of W+W_+ and W−W_- are both equal to the absolutely continuous subspace of HH.
  3. Scattering operator: when W±W_\pm exist, S=W+∗W−S = W_+^* W_- maps the free state that describes the system as t→−∞t \to -\infty to the free state that describes it as t→+∞t \to +\infty.

Remarks

When they exist, W±W_\pm are partial isometries from the absolutely continuous subspace of H0H_0 onto their ranges, and they satisfy eisHW±=W±eisH0e^{isH} W_\pm = W_\pm e^{isH_0} for all s∈ℝs \in \R. Some authors use the opposite sign convention, with W±W_\pm defined by the limit t→∓∞t \to \mp\infty. Example: ℋ=L2(ℝ3)\mathcal{H} = L^2(\R^3), H0=−ΔH_0 = -\Delta and H=−Δ+VH = -\Delta + V with VV real and ∣V(x)∣≤C(1+∣x∣)−1−ε\abs{V(x)} \le C(1 + \abs{x})^{-1-\varepsilon} for some C,ε>0C, \varepsilon > 0; then the wave operators exist and are asymptotically complete. Non-example: for the Coulomb potential V(x)=c/∣x∣V(x) = c/\abs{x} with c≠0c \ne 0, the limits in clause 1 do not exist. One needs modified wave operators, introduced by Dollard, which correct the free dynamics by a logarithmic phase. The unitary groups e−itHe^{-itH} and e−itH0e^{-itH_0} are the solutions of the time-dependent Schrödinger equations of HH and H0H_0.

Reading path

To understand this page from the ground up, read these 5 pages in order. The foundations come first.

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Each page uses the pages above it. The colour of the bar on a box shows how strong the evidence is, and the box also gives it as text. The list has the same pages.
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  1. Hamiltonian operator concept
  2. Hilbert space concept
  3. Self-adjoint operator concept
  4. Unitary operator concept
  5. Scattering theory definition

Further reading

  1. Web https://en.wikipedia.org/wiki/Scattering
About this page
TagWW0YQYY1SF
URIm2://WW0YQYY1SF
Kinddefinition
WritingW0 stub
MSC81U99, 47A40, 35P25
DefinesScattering theory
UsesHilbert space, Self-adjoint operator, Unitary operator, Hamiltonian operator
Changed3 November 2026

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