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Statistical mechanics, structure of matter Definition

Chapman–Enskog theory

Builds on Boltzmann equationMaxwell–Boltzmann distributionKinetic theory of gasesKnudsen numberEuler equationsNavier–Stokes equations

Definition

Consider the Boltzmann equation in the scaling ∂tf+v⋅∇xf=1εQ(f,f),\partial_t f + v \cdot \nabla_x f = \frac{1}{\varepsilon} Q(f, f), where ε>0\varepsilon > 0 is the Knudsen number and QQ is the collision operator. Let ρ\rho, uu and TT be the density, bulk velocity and temperature of ff, as in the kinetic theory of gases. The Chapman–Enskog expansion seeks solutions of the form f=f(0)+εf(1)+ε2f(2)+⋯f = f^{(0)} + \varepsilon f^{(1)} + \varepsilon^2 f^{(2)} + \cdots subject to the following conditions.

  1. Each f(j)f^{(j)} depends on (t,x)(t, x) only through ρ\rho, uu, TT and their spatial derivatives at (t,x)(t, x).
  2. f(0)f^{(0)} is the local Maxwell–Boltzmann distribution with the fields ρ\rho, uu, TT, and f(j)f^{(j)} for j≥1j \ge 1 has zero mass, momentum and energy moments.
  3. The fields obey conservation laws whose fluxes are expanded in the same way, ∂t=∂t(0)+ε∂t(1)+⋯\partial_t = \partial_t^{(0)} + \varepsilon \partial_t^{(1)} + \cdots, and each order is solved in turn.

Chapman–Enskog theory is the derivation of fluid equations from this expansion by truncation at a given order.

Remarks

Truncation at order 00 gives the compressible Euler equations. Truncation at order 11 gives the compressible Navier–Stokes equations with Fourier heat conduction. The viscosity and the heat conductivity are given by solutions of linear integral equations with the linearized collision operator. Truncation at order 22 gives the Burnett equations, which have known instabilities.

Example: for the BGK operator Q(f)=ν(M[f]−f)Q(f) = \nu(M[f] - f) the order-11 equation can be solved explicitly, f(1)=−ν−1(∂t(0)+v⋅∇x)f(0)f^{(1)} = -\nu^{-1}\big( \partial_t^{(0)} + v \cdot \nabla_x \big) f^{(0)}. This gives Navier–Stokes equations with Prandtl number 11.

Non-example: the Hilbert expansion also writes ff as a power series in ε\varepsilon. But its coefficients are functions of (t,x,v)(t, x, v) not tied to the fluid fields, so it fails clause 1.

Reading path

To understand this page from the ground up, read these 7 pages in order. The foundations come first.

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  1. Boltzmann equation concept
  2. Euler equations concept
  3. Kinetic theory of gases concept
  4. Knudsen number concept
  5. Maxwell–Boltzmann distribution concept
  6. Navier–Stokes equations concept
  7. Chapman–Enskog theory definition

Further reading

  1. Web https://en.wikipedia.org/wiki/Chapman%E2%80%93Enskog_theory
About this page
TagTX0C8EQE7S
URIm2://TX0C8EQE7S
Kinddefinition
WritingW0 stub
MSC82C40, 76P05, 35Q20
DefinesChapman–Enskog theory
UsesBoltzmann equation, Maxwell–Boltzmann distribution, Kinetic theory of gases, Knudsen number, Euler equations, Navier–Stokes equations
Changed3 November 2026

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