Statistical mechanics, structure of matter Definition
Chapman–Enskog theory
Builds on Boltzmann equationMaxwell–Boltzmann distributionKinetic theory of gasesKnudsen numberEuler equationsNavier–Stokes equations
Definition
Consider the Boltzmann equation in the scaling where is the Knudsen number and is the collision operator. Let , and be the density, bulk velocity and temperature of , as in the kinetic theory of gases. The Chapman–Enskog expansion seeks solutions of the form subject to the following conditions.
- Each depends on only through , , and their spatial derivatives at .
- is the local Maxwell–Boltzmann distribution with the fields , , , and for has zero mass, momentum and energy moments.
- The fields obey conservation laws whose fluxes are expanded in the same way, , and each order is solved in turn.
Chapman–Enskog theory is the derivation of fluid equations from this expansion by truncation at a given order.
Remarks
Truncation at order gives the compressible Euler equations. Truncation at order gives the compressible Navier–Stokes equations with Fourier heat conduction. The viscosity and the heat conductivity are given by solutions of linear integral equations with the linearized collision operator. Truncation at order gives the Burnett equations, which have known instabilities.
Example: for the BGK operator the order- equation can be solved explicitly, . This gives Navier–Stokes equations with Prandtl number .
Non-example: the Hilbert expansion also writes as a power series in . But its coefficients are functions of not tied to the fluid fields, so it fails clause 1.
Reading path
To understand this page from the ground up, read these 7 pages in order. The foundations come first.
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- no evidence level
- Boltzmann equation concept
- Euler equations concept
- Kinetic theory of gases concept
- Knudsen number concept
- Maxwell–Boltzmann distribution concept
- Navier–Stokes equations concept
- Chapman–Enskog theory definition
Further reading
About this page
| Tag | TX0C8EQE7S |
|---|---|
| URI | m2://TX0C8EQE7S |
| Kind | definition |
| Writing | W0 stub |
| MSC | 82C40, 76P05, 35Q20 |
| Defines | Chapman–Enskog theory |
| Uses | Boltzmann equation, Maxwell–Boltzmann distribution, Kinetic theory of gases, Knudsen number, Euler equations, Navier–Stokes equations |
| Changed | 3 November 2026 |
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