Math 2.0

Statistical mechanics, structure of matter Nonequilibrium statistical mechanics Conjecture

Eigenstate thermalization hypothesis

Builds on Microcanonical ensembleErgodic hypothesisSelf-adjoint operator

Statement

Let HH be the Hamiltonian of an isolated quantum many-body system of size NN that is non-integrable (chaotic), with eigenvalues EnE_n and orthonormal eigenvectors ∣En⟩\lvert E_n \rangle. Let AA be a local, or few-body, self-adjoint operator. The eigenstate thermalization hypothesis concerns eigenstates in the bulk of the spectrum. For them it asserts that ⟨Em∣A∣En⟩=𝒜(Eˉ) δmn+e−S(Eˉ)/2fA(Eˉ,ω) Rmn,\langle E_m \rvert A \lvert E_n \rangle = \mathcal{A}(\bar E)\, \delta_{mn} + e^{-S(\bar E)/2} f_A(\bar E, \omega)\, R_{mn}, where Eˉ=(Em+En)/2\bar E = (E_m + E_n)/2 and ω=En−Em\omega = E_n - E_m. Here 𝒜\mathcal{A} and fAf_A are smooth functions, and S(E)S(E) is the thermodynamic entropy at energy EE. The numbers RmnR_{mn} behave like random variables of mean 00 and variance 11. Moreover, 𝒜(E)\mathcal{A}(E) equals the microcanonical ensemble average of AA at energy EE, up to corrections that vanish as N→∞N \to \infty.

Remarks

The diagonal part implies that the long-time average of ⟨A⟩\langle A \rangle in any initial state with a narrow energy distribution equals the microcanonical value. The exponentially small off-diagonal part implies that the fluctuations around this average are small at most times. So isolated quantum systems thermalize in the sense of local observables, without any appeal to the ergodic hypothesis in phase space. The hypothesis was proposed by Deutsch in 1991 and by Srednicki in 1994, and the matrix-element form above is due to Srednicki (1999). It is not proved for any interacting many-body Hamiltonian of physical interest; numerical exact diagonalization supports it in many models. It fails for integrable systems, which have extensive families of conserved quantities, and is expected to fail in many-body localized systems.

Reading path

To understand this page from the ground up, read these 4 pages in order. The foundations come first.

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  1. Ergodic hypothesis concept
  2. Microcanonical ensemble concept
  3. Self-adjoint operator concept
  4. Eigenstate thermalization hypothesis conjecture

Further reading

  1. Web https://en.wikipedia.org/wiki/Eigenstate_thermalization_hypothesis
About this page
TagRAPF0XSNX9
URIm2://RAPF0XSNX9
Kindconjecture
WritingW0 stub
MSC82C10, 82B10, 81Q50
StatusThis copy of the site has no build data. Run m2 status RAPF0XSNX9.
AboutMicrocanonical ensemble
UsesMicrocanonical ensemble, Ergodic hypothesis, Self-adjoint operator
Same as
Changed3 November 2026

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