Classical thermodynamics, heat transfer Definition
Enthalpy method for phase change
Builds on Stefan problemEnthalpyLatent heatThermal conductivityWeak solution
Definition
Let be a domain filled with a material that melts at temperature . Assume for simplicity that solid and liquid have the same density , specific heat and thermal conductivity . Let be the latent heat per unit mass. Let be the enthalpy per unit volume, measured from the solid at . The temperature as a function of enthalpy is The enthalpy formulation of the Stefan problem is the equation It is understood in the weak sense, with the initial enthalpy and boundary conditions for . The enthalpy method is the numerical solution of this single equation for on a fixed grid, with the temperature recovered as . The solid region is , the liquid region is , and the set contains the phase boundary.
Remarks
Where the solution is smooth and away from the front, the equation is the heat equation . Across a sharp front, the weak form encodes the Stefan condition that the jump of the heat flux equals times the normal speed of the front. Example: an explicit scheme in one dimension updates with . A cell with has temperature and is half melted, since its liquid fraction is . Non-example: a front-tracking method moves a grid point with the interface and imposes the Stefan condition there. It is not an enthalpy method, because it treats the front as an explicit unknown. The function is continuous and nondecreasing but not strictly increasing, so the equation is a degenerate parabolic equation.
Reading path
To understand this page from the ground up, read these 9 pages in order. The foundations come first.
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- no evidence level
- Enthalpy concept
- Heat equation concept
- Latent heat concept
- Partial differential equation concept
- Thermal conductivity concept
- Weak derivative concept
- Stefan problem problem
- Weak solution definition
- Enthalpy method for phase change definition
Further reading
About this page
| Tag | NWTYMKXCCB |
|---|---|
| URI | m2://NWTYMKXCCB |
| Kind | definition |
| Writing | W0 stub |
| MSC | 80A22, 80M20, 35R35 |
| Defines | Enthalpy method for phase change |
| Uses | Stefan problem, Enthalpy, Latent heat, Thermal conductivity, Weak solution |
| Changed | 3 November 2026 |
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