Math 2.0

Statistical mechanics, structure of matter Definition

Order parameter

Builds on Gibbs measureIsing model

Definition

Let Ω\Omega be the configuration space of a lattice system, and let KK be a group acting on Ω\Omega that leaves the Hamiltonian invariant. Let VV be a finite-dimensional real vector space with a linear representation ρ\rho of KK. Assume that 00 is the only vector of VV fixed by all ρ(k)\rho(k). Let f ⁣:Ω→Vf \colon \Omega \to V be a bounded observable with f(kω)=ρ(k)f(ω)f(k \omega) = \rho(k) f(\omega) for all k∈Kk \in K and ω∈Ω\omega \in \Omega. Let μ\mu be an equilibrium state, that is an infinite-volume Gibbs measure. The order parameter of μ\mu is the vector ⟨f⟩μ=∫f dμ\langle f \rangle_\mu = \int f \, d\mu in VV. The state μ\mu is disordered if ⟨f⟩μ=0\langle f \rangle_\mu = 0 and ordered if ⟨f⟩μ≠0\langle f \rangle_\mu \ne 0.

Remarks

If μ\mu is invariant under KK, then ⟨f⟩μ=ρ(k)⟨f⟩μ\langle f \rangle_\mu = \rho(k) \langle f \rangle_\mu for all kk, so ⟨f⟩μ=0\langle f \rangle_\mu = 0. Hence an ordered state breaks the symmetry KK.

Example: for the Ising model on ℤd\Z^d with zero field, K=ℤ/2K = \Z/2 acts by the global flip σ↦−σ\sigma \mapsto -\sigma, V=ℝV = \R, ρ\rho is the sign representation and f(σ)=σ0f(\sigma) = \sigma_0. The flip sends σ0\sigma_0 to −σ0-\sigma_0, so the equivariance holds. The order parameter is the magnetization ⟨σ0⟩\langle \sigma_0 \rangle; at low temperature in the plus state it equals the spontaneous magnetization, which is positive for d≥2d \ge 2.

Non-example: the energy observable f(σ)=σ0σe1f(\sigma) = \sigma_0 \sigma_{e_1} is unchanged by the flip. The trivial representation fixes every vector, which fails the condition on ρ\rho, and indeed ⟨σ0σe1⟩>0\langle \sigma_0 \sigma_{e_1} \rangle > 0 at every temperature.

For the classical Heisenberg model, K=SO(3)K = SO(3) and the order parameter is a vector in ℝ3\R^3.

Reading path

To understand this page from the ground up, read these 3 pages in order. The foundations come first.

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Further reading

  1. Web https://en.wikipedia.org/wiki/Phase_transition
About this page
TagJM6VKSD84P
URIm2://JM6VKSD84P
Kinddefinition
WritingW0 stub
MSC82B26, 82B20
DefinesOrder parameter
UsesGibbs measure, Ising model
Changed3 November 2026

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