Statistical mechanics, structure of matter Definition
Transfer matrix method
Definition
Let be a finite set of single-site states, let be a nearest-neighbour energy and let be the inverse temperature. Consider the periodic chain of sites with energy The transfer matrix is the matrix with entries . The transfer matrix method is the evaluation of the partition function through the identity which follows by expanding the trace of the matrix product.
Remarks
If are the eigenvalues of , then . Since has positive entries, the Perron–Frobenius theorem makes simple and strictly larger than the other moduli, so . Connected correlations typically decay like at distance , so the correlation length is . Example: the Ising chain with on has and for its eigenvalues are and . Non-example: a chain in which each site interacts with all other sites is not covered. Its energy is not a sum of terms in neighbouring pairs, and one would need states of unbounded size. In two dimensions one takes to be the set of configurations of a whole row, which turns the method into a large eigenvalue problem.
Reading path
To understand this page from the ground up, read these 6 pages in order. The foundations come first.
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- no evidence level
- Boltzmann distribution concept
- Eigenvalue concept
- Matrix definition
- Square matrix definition
- Trace of a matrix definition
- Transfer matrix method definition
Further reading
About this page
| Tag | NJ41GD4C0R |
|---|---|
| URI | m2://NJ41GD4C0R |
| Kind | definition |
| Writing | W0 stub |
| MSC | 82B20, 82B23 |
| Defines | Transfer matrix method |
| Uses | Trace of a matrix, Eigenvalue, Boltzmann distribution |
| Changed | 3 November 2026 |
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