Math 2.0

Mechanics of deformable solids Definition

Electroactive polymer

Builds on Solid mechanics

Definition

An electroactive polymer is a polymer material that deforms in a reversible way under an applied electric field or electric current. Two classes are usual.

  1. Electronic electroactive polymers deform under the electric field itself, for example dielectric elastomers and electrostrictive or ferroelectric polymers.
  2. Ionic electroactive polymers deform because ions move inside the material, for example ionic polymer–metal composites, conducting polymers and ionic gels.

Remarks

Example: a dielectric elastomer film of thickness dd with compliant electrodes on both faces. A voltage VV across the film gives an electric field E=V/dE = V/d. The attraction of the electrodes acts as an effective pressure p=ε0εrE2p = \varepsilon_0 \varepsilon_r E^2 on the film, where ε0\varepsilon_0 is the vacuum permittivity and εr\varepsilon_r the relative permittivity of the polymer. The film is a polymer and it deforms reversibly under the field, so it satisfies the definition.

Non-example: a ceramic piezoelectric crystal such as lead zirconate titanate also deforms under an electric field, but it is not a polymer.

The terms "artificial muscle" and "EAP" are common names for these materials.

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Further reading

  1. Web https://en.wikipedia.org/wiki/Electroactive_polymer
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MSC74F15, 74M05
DefinesElectroactive polymer
UsesSolid mechanics
Changed3 November 2026

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